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程序涂渍气相色谱柱测定多元醇的研究

A Study of Gradient Loaded Column Gas Chroma- tography for Determination of Polyhydric Alcohols

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【作者】 李钦祖郑竹莲陈怀瑛

【Author】 Li Qinzu, Zheng Zhulian and Chen Hnaiying Department of Chemical Engineering, Zhejiang Institute of Technology, Hangzhou

【机构】 浙江工学院化工系浙江工学院化工系 杭州杭州杭州

【摘要】 <正> In this paper, the characteristics of separating xylitol, arabinitol and sorbitol with uniformly loaded columns containing 2,5,7 and 9wt% XE-60 and gradient loaded columns are compared in detail. The suspended chain curve formulaY=en (x-a/2) +e-n (x-a/2) is suggested for calculation of amount of different coated packing in the gradient loaded column, where selector coefficient n=l.l, a is average liquid loading amount, x is individual liquid loading amount. The gradient loaded column can not only satisfactorily separate isomers of xylitol and arabinitol, but also shorten retention time of sorbitol obviously.

【Abstract】 In this paper, the characteristics of separating xylitol, arabinitol and sorbitol with uniformly loaded columns containing 2,5,7 and 9wt% XE-60 and gradient loaded columns are compared in detail. The suspended chain curve formulaY=en (x-a/2) +e-n (x-a/2) is suggested for calculation of amount of different coated packing in the gradient loaded column, where selector coefficient n=l.l, a is average liquid loading amount, x is individual liquid loading amount. The gradient loaded column can not only satisfactorily separate isomers of xylitol and arabinitol, but also shorten retention time of sorbitol obviously.

  • 【文献出处】 色谱 ,Chinese Journal of Chromatography , 编辑部邮箱 ,1989年04期
  • 【被引频次】4
  • 【下载频次】30
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