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2-甲基二十酸的合成及其润滑性
Synthesis and Lubricty of 2-Methyleicosanoic acid
【摘要】 本文研究了由1-十八醇合成2-甲基二十酸及产物的润滑性。1-十八醇与冰醋酸经酯化反应得到醋酸十八酯、再裂解成1-十八烯,收率78%。1-十八烯与丙酸经自由基加成得2-甲基二十酸,收率45%。产物的润滑性优于油酸,起泡性大大低于油酸。
【Abstract】 The papar has studied Synthesis of 2-methyleicosanoic acid from 1-octadecanol and lubrity of product, 1-octadecanol and glacial acetic acid after esterification gave the octadecyl acetate, then was pyroted to obtain 1-octadecene, with yield was 78%. 1-octadecene and propanoic acid by free-radical addition gave 2-methyleicosanoic acid, with yield was 45%, Lubricity of product prevail over the oleic acid, and its foamability is much low than the oleic acid.
- 【文献出处】 润滑与密封 ,Lubrication Engineering , 编辑部邮箱 ,1989年03期
- 【被引频次】5
- 【下载频次】58