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含硫的聚硅氧烷树脂的合成和吸附性能的研究
STUDY ON SYNTHESIS AND ADSORPTION PROPERTIES OF POLYSILOXANE RESINS CONTAINING SULFUR
【作者】
洪满水;
邱南飞;
郭莲灯;
【Author】
Hong Manshui Qiu Nanfei Guo Liandeng (Department of Chemistry, Xiamen University) polysiloxanes(C) containing 3-bromopropyl were synthesized by cohydrolysis of 3-bromopropyl methyl dichlorosilane monomer(A) and 2-(acetoxy)ethyl methyl dichlorosilane monomer(B). Polysiloxanes(D) containing sulfur were obtained by reaction of (C) with sodium hydro-sulphide and 2-mercaptoethanol respectively. Porous polysiloxane resins(SSR) containing sulfur were then obtained by bbbbbbbbbbbbbbbbbbbbbbb-elimination and cross-linking in the chain element of (B). The physical properties and soption capacities of (SSR) were determined.
【机构】
厦门大学化学系;
厦门大学化学系;
【摘要】 由3—溴丙基甲基二氯硅烷单体(A)和2-(乙酰氧基)乙基甲基二氯硅烷单体(B)共水解,制得含3—溴丙基的聚硅氧烷(C)。(C)分别与硫氢化钠和2-巯基乙醇反应,获得了含硫的聚硅氧烷(D);经β—消除和交联缩聚,合成了含硫的多孔性聚硅氧烷吸附树脂(SSR)。测定了(SSR)的一些物性和对金属离子的吸附性能。更多还原
【基金】 国家自然科学基金
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【文献出处】
离子交换与吸附
,Ion Exchange and Adsorption
,
编辑部邮箱
,1989年06期
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