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丙烷正己烷混合气体的红外同时分析——卡尔曼滤波与多波长线性回归法
SIMULTANEOUS DETERMINATION OF GAS MIXTURES CONTAINING PROPANE AND N-HEXANE BY IR SPECTROMETRY——APPLICATION OF THE KALMAN FILTER AND MULTI-WAVELENGTH REGRESSION METHOD
【摘要】 在3040~2800cm-1范围内,丙烷、正已烷的红外吸收光谱相互重叠严重,本文利用自编的卡尔曼滤波与多波长线性回归方法程序(Turbo PASCAL语言,4.0版本)进行丙烷、正已烷混合气体红外吸收光谱的分离,采样间隔为5或10cm-1,共采样30个点。对8个不同配比的标准混合气体进行分析,结果表明两种算法所得结果相近,相对偏差大多在±5%左右。
【Abstract】 Severly overlapped IR spectra of propane and n-hexane were obtained in the range of 3040 to 2800cn-1, In this paper, the overlapped IR spectra of propane and n-hexane were resolved by the Kalman filter(KF) and multi-wavelength regression (MWR) method respectively. The programs were written in Turbo PASCAL language (ver 4.0) and ran on the IBM PC/AT microcomputer. The IR spectral data were measured on a HITACHI 270-50 IR Spectrometer. 30 points were digitized in the range of 3040 to 2800 cm-1 with the sampling interval of 5 or 10cm-1. 8 standard mixture samples were analyzed with the relative deviation of about ±5%.
- 【文献出处】 理化检验.化学分册 ,Physical Testing and Chemical Analysis(Part B:Chemical Analysis) , 编辑部邮箱 ,1989年03期
- 【分类号】O657.3
- 【下载频次】12