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丙烷正己烷混合气体的红外同时分析——卡尔曼滤波与多波长线性回归法

SIMULTANEOUS DETERMINATION OF GAS MIXTURES CONTAINING PROPANE AND N-HEXANE BY IR SPECTROMETRY——APPLICATION OF THE KALMAN FILTER AND MULTI-WAVELENGTH REGRESSION METHOD

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【作者】 钱锋; 石乐明; 李志良;

【Author】 Qian Feng (Standard Gas Mixtures Center, Beijing Analytical Instrument Factory, Belling) Shi Leming (Computer Center, Institute of Chemical Metallurgy Academia Sintcal Li Zhiliang (Department of Chemistry and Chemical Engineering, Hunan University, Changsha)

【机构】 北京分析仪器厂配气站; 中科院化工冶金所计算中心; 湖南大学化学化工系;

【摘要】 在3040~2800cm-1范围内,丙烷、正已烷的红外吸收光谱相互重叠严重,本文利用自编的卡尔曼滤波与多波长线性回归方法程序(Turbo PASCAL语言,4.0版本)进行丙烷、正已烷混合气体红外吸收光谱的分离,采样间隔为5或10cm-1,共采样30个点。对8个不同配比的标准混合气体进行分析,结果表明两种算法所得结果相近,相对偏差大多在±5%左右。

【Abstract】 Severly overlapped IR spectra of propane and n-hexane were obtained in the range of 3040 to 2800cn-1, In this paper, the overlapped IR spectra of propane and n-hexane were resolved by the Kalman filter(KF) and multi-wavelength regression (MWR) method respectively. The programs were written in Turbo PASCAL language (ver 4.0) and ran on the IBM PC/AT microcomputer. The IR spectral data were measured on a HITACHI 270-50 IR Spectrometer. 30 points were digitized in the range of 3040 to 2800 cm-1 with the sampling interval of 5 or 10cm-1. 8 standard mixture samples were analyzed with the relative deviation of about ±5%.

  • 【文献出处】 理化检验.化学分册 ,Physical Testing and Chemical Analysis(Part B:Chemical Analysis) , 编辑部邮箱 ,1989年03期
  • 【分类号】O657.3
  • 【下载频次】12
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