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PH-电位法测定多元配合物稳定常数的计算程序
A Computer Program for Calculating Stability Constants of Polynary Complexes from PH-Potentiometric Measurements
【摘要】 本文扩展了应用于测定二元配合物稳定常数的 TITFIT 程序,使之适用于形成多元配合物的平衡体系。通常滴定曲线的函数误差(滴定 NaOH 的总体积 ml)σml<0.5%。适合曲线的最好参数与文献值列于表,我们的结果与文献上的相符较好。
【Abstract】 We have developed a computer program TITFIT which was used to calculating stabili-ty constants of binary complexes.The developed program can be applied to the equilibriumsystem containing polynary complexes.In general we can fit titration curves with the errorlower than 0.5% of the total volume of the titrant.The best parameters used for fitting,together with those published in the literature,are given in table 1.These results coin-cide with those already published in the literatures
【关键词】 多元配合物;
稳定常数;
PH-电位法;
【Key words】 Polynary complexes; PH-potentiometric measurements; Stability constants;
【Key words】 Polynary complexes; PH-potentiometric measurements; Stability constants;
- 【文献出处】 计算机与应用化学 ,Computers and Applied Chemistry , 编辑部邮箱 ,1989年02期
- 【被引频次】2
- 【下载频次】110