节点文献
光化学法控制Np价态的研究——Ⅰ.Np(Ⅵ)的光化还原动力学
STUDY ON CONTROLLING THE VALENCE STATE OF NEPTUNIUM BY PHOTOCHEMISTRY Ⅰ. THE PHOTOREDUCTION KINETICS OF Np(Ⅵ)
【摘要】 本文研究了硝酸体系中,酸度,Np(Ⅵ)初始浓度和温度等因素对Np(Ⅵ)光化还原速率的影响。推导出Np(Ⅵ)的光化还原速率方程式 -((d[Np(Ⅵ)])/dt)=0.05766[Np(Ⅵ)][H+]-1所提出的反应机理能较好地符合实验结果。
【Abstract】 The influence of the initial concentration of Np(Ⅵ) in nitric acid solution, temperature and acidity etc. on the photoreduction of Np(Ⅵ) has been studied in detail with mercury lamp. The rate equation of photoreduction of Np(Ⅵ) is formulated as follows._d[Np(Ⅵ)]/dt =0.05766[Np(Ⅵ)][H+]-1The photochemical reaction mechanism of Np suggested in this system can be interpreted satisfactorily by the experimental results.
【关键词】 镎;
光化还原;
速率方程;
反应机制;
【Key words】 Neptunium; Photoreduction; Rate equation; Mechanism of reaction.;
【Key words】 Neptunium; Photoreduction; Rate equation; Mechanism of reaction.;
- 【文献出处】 核化学与放射化学 ,Journal of Nuclear and Radiochemistry , 编辑部邮箱 ,1989年02期
- 【被引频次】2
- 【下载频次】43