【摘要】 本文用emf法通过测定得到Pt,H₂（latm）Hcl（xm）+H₂O|AgCl—Ag及Pt,H₂（latm）I HCl（xm）+40Wt%DMSO+H₂O/AgCl—Ag两电池的标准电动势E°及其温度系数。求出盐酸从H₂O到40Wt%DMSO—H₂O混合溶剂的迁移自由能ΔGtr、迁移焓ΔHtr、迁移熵ΔStr及迁移活度系数^wγ^s。进而求出盐酸在40Wt%DMS0—H₂O混合溶剂中的标准生成自由能ΔfG°（298.15）。更多还原

【Abstract】 Electromotive force measurements of cells Pt,H₂（latm）|HCl（xm）+H₂O|AgCl—Ag and Pt,H₂（latm）|HCl（xm）+40Wt%DMSO—H₂O|AgCl—Ag atthree temperatures ranging from 25 to 45℃,were used to derive thestandard emf of the cells and temperature coeficients of emf.Wehave calculated the transfer free energies,transfer enthalpies and transferssactivity coeficients of HCl form water to 40Wt%DMSO—H₂O mixed solventcalculated and the standard formation free energy Δ_fG°（298.15）of HClmixed solvents.更多还原