【摘要】 本文通过逐级取代反应,合成了三种新的含有1,1-二（二苯基膦）二茂铁（dppf）配体的π-键合混合配体零价钯双核配合物,并用红外光谱,元素分析,电子光谱,¹H-NMR及³¹P-NMR对其进行了表征.利用循环伏安法测得三个配合物的茂基Fe（Ⅱ）的氧化还原电位.提出了它们的可能结构.更多还原

【Abstract】 Three new π-bonding mixed-ligand Pd（O）binuclear complexes with dppf ligands were prepared through step-by-step substitution reactions.These complexes were characterized through elemental analysis,IR,electronic and H-NMR,³¹P-NMR spectra.Their redox wave peak potentials of the ferrocenyl group were measured by using CV method.The probable structures of these new complexes were proposed.更多还原