【摘要】 本文研究了水溶性和油溶性阻聚剂对第Ⅱ类动力学乳液聚合的影响(以苯乙烯乳液聚合为例).实验结果表明阻聚剂对胶粒的形成及增长有明显的影响.推导出反映这些影响的数学模型,并对阻聚剂的影响进行了模拟研究,指出阻聚剂的这些行为在工业乳液聚合中的严重性.更多还原

【Abstract】 The effect of water soluble and monomer soluble inhibitors on the kinetics of emulsion polymerization of monomer following Case II kinetics (e. g. styrene) has been investigated. Experimental studies reveal that inhibitors can bave an appreciable effect on both polymer particle nucleation and growth. A mathematical model showing these effects has been developed and simulation studies have been made. The simulation results imply that the behaviour of monomer soluble inhibitors may be severe in industrial emulsion polymerization.更多还原