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熔盐籽晶法生长三硼酸锂单晶
GROWTH OF LITHIUM TRIBORATE SINGLE GRYSTALS BY FLUX SEEDING METHOD
【摘要】 <正> 一、引言 三硼酸锂晶体(LiB3O5,简称LBO)属正交晶系,空间群为P21cn,晶胞参数a=5、141(6)(?),b=7.378(4)(?),c=8.446(3)(?),z=4,密度为2.48g/cm3,Moh′S硬度约为6。它是我所继发现β-BaB2O4晶体(BBO)之后,又首先发现的一种新型非线性光学
【Abstract】 The plate-shape lithium triborate single crystals with a dimension of 38×24×4 mm have been grown by the flux seeding method, using a self-flux B2O3 of composition LiB3O5:B2O3=2:1 (mol) at a constant temperature for a long time and then cooled very slowly. Though the self-flux has the advantage of avoiding contamination to the crystal, the viscosity of the solution is so high that it is very difficult to increase the growth rate for large crystals. Therefore, efforts have been achieved in this respect. Finally, a large crystal up to 37×25×13 mm of superior quality has been grown using this new flux.
- 【文献出处】 硅酸盐学报 ,Journal of The Chinese Ceramic Society , 编辑部邮箱 ,1989年02期
- 【被引频次】2
- 【下载频次】90