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水中钒的催化示波极谱测定法——钒—过硫酸铵—苯羟乙酸—硫酸新体系
CATALYTIC OSCILLOSCOPIC POLAROGRAPHY FOR DETERMINATION OF VANADIUM IN WATER
【摘要】 本文基于在硫酸介质及100℃水浴加热条件下,痕量钒(V)对过硫酸铵氧化苯羟乙酸生成电活性物质苯甲醛这一慢反应的选择催化作用,建立了一个可测范围为0.04ng/ml-8.0ng/ ml,灵敏快速、选择性较佳的测定水中钒的催化示波极谱法。
【Abstract】 We find the catalytic oscilloscopic polarography way for determination of Ⅴ in water on the basis of vanadic selective catalytic action in the slow reaction which produces a benzaldehyde compound by ammonium persulfate oxidating benzcnegydro acid.The mcthos has an advantage of high sensitivity,speed and selective action,and can be used to analyse Ⅴ in the concentration scale from 0.04 to 8.00(ng / ml).
- 【文献出处】 干旱环境监测 ,Arid Environmental Monitoring , 编辑部邮箱 ,1989年04期
- 【被引频次】2
- 【下载频次】19