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羧酸铝盐活性填料补强交联聚乙烯的研究

STUDY ON REINFORCEMENT OF CROSSLINKED POLYETHYLENE WITH REACTIVE ALUMINIUM CARBOXYLATES FILLER

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【作者】 林明德俞强方正国杨长来张亚科徐惠全

【Author】 Lin Mingde, Yu Qiang, Fang Zhengguo, Zhang Yake, Yang Changlai and Xu Huijin, (Jiangsu Institute of Chemical Technology)

【机构】 江苏化工学院高分子材料教研室江苏化工学院高分子材料教研室江苏化工学院高分子材料教研室 本院八六届毕业生本院八七届毕业生本院八七届毕业生

【摘要】 本工作合成了数种羧酸铝盐类反应性填料,发现内中丙烯酸铝及甲基丙烯酸铝对于交联聚乙烯具有良好的补强作用。笔者研究了活性填料的用量及比表面对补强效果的影响。溶胀、萃取、DSC及动态力学性能测定的结果表明:交联聚乙烯与反应性填料之间存在交联以及接枝之类的化学反应。

【Abstract】 The reinforcing effects of various Aluminum Carboxylates on crosslinked polyethylene were studied. It was found that the reinforcing effect of Aluminum acrylate is superior to those of the other Aluminum derivatives. An increase of 50% tensile strength of crosslinked polyethylene can be obtained by adding 20phr of Aluminum acrylate. The measurement of specific surface area showed that the greater the specific surface area of reactive filler, the better the reinforcing effect will be. Utilizing methods such as swelling measurement, Sox-hlet extraction, DSC and dynamic mechanical measurement, we have investigated the reinforcing mechanisms of Aluminum acrylate on crosslinked polyethylene.lt seems that the reinforcing effects may be resulted from the crosslinking and grafting reactions between polyethylene and Aluminum reactive filler.

  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,1989年04期
  • 【被引频次】15
  • 【下载频次】90
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