【摘要】 本文研究了酸性亚磷酸酯与α-芳基-β-硝基烯烃在三甲基氯硅烷和缚酸剂存在下的Arbuzov-Michael反应。不需制备硅烷化的亚磷酸酯,即可得到产率高的I_a-n,其结构由元素分析、IR、¹H NMR和MS证实。这类分子中磷原子上的O,O-二烷基为磁不等价基团的结论亦为X-射线晶体结构分析所证实。更多还原

【Abstract】 This paper reports a one-pot reaction of the Arbuzov-Michael addition of acidic phosphites to α-aryl-β-nitroalkenes. The reaction was carried out smoothly with an excess of trimethylchlorosilane and acid-binding agents, giving high yields of addition products I a-n . The structures of these compounds were characterized by elemental analysis, IR, 1H NMR and MS. It was found that in these molecules the O,O-dialkyl groups on the phosphorus atom were unequivalent. This fact was also confirmed by the X-ray structure determination of one representative compound, I j.更多还原