【摘要】 Mo（Ⅵ）在pH 2～3,0.1mol/L KCl溶液中能被还原,其电位为-0.45V（对Ag/AgCl）。还原产物能沉积在滴汞上,它能催化N0₂^-的还原。NO₂^-的还原电位从-0.95V（对Ag/AgCl）正移到-0.81V。NO₂^-还原峰电流的大小正比于它的浓度,NO₃^-在很宽的浓度范围内不干扰。本文对NO₂^-和NO₃^-在Mo存在时的极谱行为作了探讨。更多还原

【Abstract】 The reduction of Mo(Ⅵ) at -0.45V vs Ag/AgCl in a pH 2-3. Solution of 0.1 mol/1 KC1, results in a deposit on mercury electrode which catalyzes nitrite reduction. The potential of the nitrite reduction peak moves from -0.95V to -0.81V vs Ag/ AgCl. A peak is developed in direct proportion to nitrite concentration. Nitrate does not interfere in a wide concentration range. The mechanism for the Mo-catalyzed nitrite reduction is suggested.更多还原