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多元丙烯酸酯共聚物的裂解气相色谱质谱研究

Pyrolysis Gas Chromatography-Mass Spectrometry for Acrylic Multi Component Polymers Chemical Engineering College,Dalian University of Technology

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【作者】 续大义程光荣曹淑兰侯翠玢

【Author】 Xu Dayi~* Cheng Guangrong Cao Shulan Hou Cuifen (Liaoning Province Physical and Chemical Test Cetre,Shenyang)

【机构】 辽宁省分析测试研究中心大连理工大学化工学院高分子材料系

【摘要】 使用居里点裂解-气相色谱-质谱-计算机数据系统联用(PGCMSDS)研究了有机玻璃和七种丙烯酸酯多元共聚物裂解规律。讨论了 PGCMSDS 法鉴别高聚物的可行性。

【Abstract】 The various kinds of acrylic multi-component polymers (PMMA and MMA -MA,MMA-EA,MMA-BA,MMA-BA-BMA,MMA-BA-Styrene,Buta-diene -acrylonitrile-BA,MHA-EA-EMA-BMA Copolymers) were analyzed by Curie Point pyrolysis gas chromatography-mass spectrometry with data processing system (PGCMSDS).Moreover,the feasibility of the PGCMSDS method for these copolymers was discussed.The components of copolymers could be deter- mined based on the mass spectrum of the comonomer peak in.pyrogram,and the retention time is not important in PGCMSDS method.

  • 【文献出处】 质谱学报 ,Journal of Chinese Mass Spectrometry Society , 编辑部邮箱 ,1988年02期
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