节点文献
水和非水体系现场电化学-电子自旋共振测量——电解池制作和初步结果
ELECTROCHEMICAL ELECTRON SPIN RESONANCE MEASUREMENTS
【摘要】 <正> A simultaneous electrochemical-electron spin resonance(SEESR)cell has been designed. It is easily fabricated and operated and can be used for either aqueous or nonaqueous determation.Using this aparatus, the ESR signals were observed for nitrobenzcne anion radicals, produced by constant potential electrolysis of nitrobenzene in acetonitrile media with 0.1M TBAP as electrolyte and in 0.5M KCl aqueous solution respectively. The hyperfine coupling constants of the nitrobenzene anion radical have been estimated which are in accordance with the literature values.
【Abstract】 A simultaneous electrochemical-electron spin resonance(SEESR)cell has been designed. It is easily fabricated and operated and can be used for either aqueous or nonaqueous determation.Using this aparatus, the ESR signals were observed for nitrobenzcne anion radicals, produced by constant potential electrolysis of nitrobenzene in acetonitrile media with 0.1M TBAP as electrolyte and in 0.5M KCl aqueous solution respectively. The hyperfine coupling constants of the nitrobenzene anion radical have been estimated which are in accordance with the literature values.
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1988年01期
- 【被引频次】1
- 【下载频次】47