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新型锑酸镉半导瓷Cd6Sb2O10的相变
Phase Transitions of Cd6Sb2O10 Semiconductive Ceramics
【摘要】 本文报道了对新型锑酸镉半导瓷Cd6Sb2O10进行差热分析、热失重分析和高温X射线衍射分析的实验结果,并进行了系统地分析和讨论。结果表明,Cd6Sb2O10在240℃左右发生一结构相变,高温相具有较高的对称性,此相变是可逆的,从低温相向高温相转变时,相变温度为246℃,从高温相向低温相转变时,相变温度为228℃。
【Abstract】 The thermal analysis and X-ray diffraction analysis on Cdr,Sb2O10 semiconductivc ceramics are carried out systematically, and the results are discussed. It is indicated that a structural phase occurs in Cd6Sb2O10 at about 240℃ and the high temperature phase possesses a higher symmetry.The phase transition is reversible and transition temperature are 246℃ and 228℃ respectively.
【基金】 中国科学院基金资助项目
- 【文献出处】 压电与声光 ,Piezoelectrics & Acoustooptics , 编辑部邮箱 ,1988年04期
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