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轻稀土离子掺杂的硫酸三甘肽单晶体

RARE EARTH CATIONS DOPED TRIGLYCINE SULFATE SINGLE CRYSTALS

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【作者】 郑吉民; 范京富; 车云霞; 申泮文; 张世表; 朱亚平; 温金珂; 王华馥;

【Author】 Zheng Jiming Fan Jinfu Che Yunxia Shen Panwen Zhang Shibiao Zhu Yaping Wen Jinke Wang Huafu (Department of Chemistry,Department of Physics,Nankai University)

【机构】 南开大学化学系、物理系; 南开大学化学系、物理系;

【摘要】 本文确定了掺有 La3+、Ce4+、pr3+、Sm3+、Nd3+的硫酸三甘肽(TGS)晶体的生长条件。测定了晶体中不同稀土离子的掺入量和晶体的电滞回线、热释电系数、介电常数等物理参数。结果表明,TGS 单晶体中掺入适量 Pr3+可以使其热释电性能得到明显改善。

【Abstract】 Single crystals of La3+,Ce4+, Pr3+, Nd3+, Sm3+ doped triglycine sulfate havebeen grown from low temperature solutions with the slow-cooling method.Thechanges of crystal properties due to dopants are described respectively.Content ofdopants in each crystal has been determined.Values of pyroelectric coefficients,dielectric constants,loss tangents and figures of merit are listed in detail.Com-parision of the properties between the doped TGS crystals and pure TGS crystalare given.It is found that TGS single crystal doped with suitable amount of Pr3+grows easily and has better pyroelectric properties than that of pure TGS singlecrystal.At 25℃,λ=5.21×10-8C·K-1·cm-2, εr=28.7,tanδ=1.74×10-3 and the fi-gure of merit is 1.81×10-9C·K-1·cm-2 when the molar concentration of Pr3+ is1.05%.

  • 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,1988年03期
  • 【被引频次】13
  • 【下载频次】48
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