【摘要】 在非水介质中合成出1,8-萘啶氮氧化物与6个3d元素(锰,铁,钴,镍,铜,锌)高氯酸盐的固体配合物.对配合物进行了熔点及溶解性测定.通过元素分析、红外光谱、紫外光谱和摩尔电导等测定.研究了配合物的组成和性质.更多还原

【Abstract】 The solid complexes of 3d metal perchlorates with 1, 8-naphthyridine-N-oxide (napyo) having the composition Fe(napyo)4(ClO4)3, Cu(napyo)2(ClO4)2 and M(napyo)3(ClO4)2(M=Mn, Co, Ni, Zn) have been synthesized.The series of new complexes have been characterized by elemental analyses, infrared spectra, ultraviolet spectra and molar conductance. The results show that the metal ions in these complexes are coordinated to oxygen atoms and nitrogen atoms of the lig-ands and the perchlorate groups are not coordinated to the metal ions.更多还原