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硫化铁处理含铬(Ⅵ)废水的进一步研究

A Further Study on the Ferrous Sulfide Treatment of Chromium (Ⅵ) Wastewater

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【作者】 傅贤书;

【Author】 Fu Xianshu Dept.of Basic Course

【机构】 西安冶金建筑学院基础课部;

【摘要】 本文介绍了硫化铁处理铬(Ⅵ)废水的进一步研究结果。实验结果表明:铬(Ⅵ)的去除率均在99%以上,出水铬(Ⅵ)含量不仅达到废水的排放标准(≤0.5mg/L),对低浓度铬(Ⅵ)废水经硫化铁处理后还能达到饮用水标准(≤0.05mg/L)。与一般还原剂不同,硫化铁为难溶化合物,其中的Fe2+和S2-都是强还原剂。因此,在比较宽广的pH值(2~10)范围内,铬(Ⅵ)均可被还原成铬(Ⅲ)而除去,且无二次污染。实验结果还说明,硫化铁除铬(Ⅵ)效果好是由于存在还原、"中和"和絮凝三种作用的结果。

【Abstract】 This paper describes the results of a further study on the ferrous sulfide treatment of chromium(Ⅵ)wastewater.The experimental results indicated that the rates of Cr(Ⅵ)removal were above 99%,and that the contents of chromium(Ⅵ) in the effluent have reached the discharge standard for wastewater(≤0.5mg/L) and even reached the standard for drinking water (≤0.05mg/L) in low-concentration wastewater.Unlike other reductants, ferrous sulfide is an insoluble compound,and it’s Fe2+ and S2- are both strong reductants.Therefore in a more extensive pH range(2-10),Cr(Ⅵ) could be removed by being reduced to Cr(Ⅲ),and there is no secondary pollution.The experimental results also indicated that such good effects are due to three coexisting reactions,i.e.reduction,neutralization and flocculution.

【关键词】 铬废水; 硫化铁; 还原; 絮凝;
【Key words】 chromium wastewater; ferrous sulfide; reduction; flocculation;
  • 【文献出处】 西安建筑科技大学学报(自然科学版) ,Journal of Xi’an University of Architecture & Technology(Natural Science Edition) , 编辑部邮箱 ,1988年01期
  • 【被引频次】3
  • 【下载频次】123
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