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硫化铁处理含铬(Ⅵ)废水的进一步研究
A Further Study on the Ferrous Sulfide Treatment of Chromium (Ⅵ) Wastewater
【摘要】 本文介绍了硫化铁处理铬(Ⅵ)废水的进一步研究结果。实验结果表明:铬(Ⅵ)的去除率均在99%以上,出水铬(Ⅵ)含量不仅达到废水的排放标准(≤0.5mg/L),对低浓度铬(Ⅵ)废水经硫化铁处理后还能达到饮用水标准(≤0.05mg/L)。与一般还原剂不同,硫化铁为难溶化合物,其中的Fe2+和S2-都是强还原剂。因此,在比较宽广的pH值(2~10)范围内,铬(Ⅵ)均可被还原成铬(Ⅲ)而除去,且无二次污染。实验结果还说明,硫化铁除铬(Ⅵ)效果好是由于存在还原、"中和"和絮凝三种作用的结果。
【Abstract】 This paper describes the results of a further study on the ferrous sulfide treatment of chromium(Ⅵ)wastewater.The experimental results indicated that the rates of Cr(Ⅵ)removal were above 99%,and that the contents of chromium(Ⅵ) in the effluent have reached the discharge standard for wastewater(≤0.5mg/L) and even reached the standard for drinking water (≤0.05mg/L) in low-concentration wastewater.Unlike other reductants, ferrous sulfide is an insoluble compound,and it’s Fe2+ and S2- are both strong reductants.Therefore in a more extensive pH range(2-10),Cr(Ⅵ) could be removed by being reduced to Cr(Ⅲ),and there is no secondary pollution.The experimental results also indicated that such good effects are due to three coexisting reactions,i.e.reduction,neutralization and flocculution.
- 【文献出处】 西安建筑科技大学学报(自然科学版) ,Journal of Xi’an University of Architecture & Technology(Natural Science Edition) , 编辑部邮箱 ,1988年01期
- 【被引频次】3
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