【摘要】 本工作测量了室温下TbP₃O₁₄和EuP₅O₁₄晶体的吸收和发射光谱。根据吸收光谱和Judd-Ofelt理论计算了Tb³⁺和Eu³⁺的实验和理论的振子强度。用最小二乘法拟合实验与理论的振子强度得到唯象强度参量Ω_λ。然后计算了Tb³⁺的⁵D₃→⁷F₅,⁵D₄→⁷F₄和⁵D₄→⁷F₆以及Eu³⁺的⁵D₀→⁷F₂,⁵D₀→⁷F₄的跃迁几率和寿命。同时用时间分辨光谱测量了不同温度下相应的荧光辐射寿命。计算与实验结果基本相符。理论和实验的结果表明Tb³⁺的⁵D₃态的寿命主要取决于⁵D₃→⁵D₄和⁷F₆→⁷F₀两能级对之间的电偶极-电偶极交叉弛豫。更多还原

【Abstract】 The absorption and fluorescence spectra of Tb3+ and Eu3+ in LnP5O14 crystals at room temperture were observed. Based on absorption spectra and Judd-Ofelt theory, experimental and theoretical oscillator strengths were calculated. Series phenomenolo-gical intensity parameters were determined according to a least-square fitting. Then a c alculation of the radiative transition probabilities and lifetimes of 5D3→7F5, 5D4→ 7F4 and 5D4→7F6 in TbP5Ol4, as well as 5D0→7F2 and 5D0→7F4 in EuP5O14 was carried out. We also obtain corresponding fluorescence lifetime by using time-resolved spectroscopy at various temperatures. The experimental results are in agreement with theoretical results. Our results confirmed that the lifetime of Tb3+5D3 depends mainly on the electric dipole-dipole cross relaxation between 5D3→5D4 and 7F6 →7F0.更多还原