【摘要】 Nd₂Fe₁₄B是一种磁能积很高的优良的永磁材料,但在实用上稍嫌它的居里温度低了一点。为了提高它的居里温度,人们曾用某些元素替代其中的一些铁作了尝试。文献[9]及我们最近的实验表明:用硅代替部分铁之后,材料的居里点都获得了提高。本文用中子衍射法研究了Si在Y₂Fe₁₄B中的占位情况,以了解Si对磁性能产生的影响。中子衍射的结果表明:Si择优地占据c,j₁及k₂晶位。最后,用磁交换作用对结果进行了讨论。更多还原

【Abstract】 The outstanding permanent magnetic material Nd2Fe14B possesses very high energy product. But its Curie temperature is a little bit too low for practical application. Some elements were added into the material in order to raise the Curie temperature. Reference [9] and our recent experimental results show that the Curie temperature can be made higher by partiy subsituting silicon for iron in the material and in Y2Fe14B. For understanding the effect of silicon on magnetism, the occupancy of Si in YzFe14B was studied by neutron diffraction. The neutron diffraction results show that silicon occupies preferentially the sites of c, j1, and k2. The magnetic interaction theory is applied to explain the experimental results.更多还原