【摘要】 本文成功地合成了插层化合物Li_1+xV₃O_,并用X射线粉末衍射和等离子体发射光谱元素定量分析进行了鉴定。同时进行了NMR研究。在298—400K之间观察到了锂离子的运动致窄效应,并以此求得它的离子运动激活能为0.18eV。还测得该材料的室温电导率为10^-3Ω^-1·cm^-1数量级。更多还原

【Abstract】 The intercalation compound Li(1+x) V3O8 has been prepared successfully and investigated by X-ray powder diffraction and quantitative element analysis. The compound was also studied with 7Li NMR (on line width) in temperature range 298-400K by using SXP4-100 NMR spectrometer at a frequency f = 35.03 MHz. The active energy of Li+ion, Ea = 0.18eV, is derived from the line width of the motional narrowing. The conductivity is 10(-3)(?)(-1)·cm-1 at room temperature.更多还原