【摘要】 合成了金（Ⅲ）与七种中性氧配体RnXO（R=辛基或苯基;X=N,P,As和S;n=2,3）形成的十种配合物,可概括为两种类型:H（RnXO）x·AuCl₄·Sy（RnXO=TONO、TOPO、TPPO、DOSO、DPSO、TPAsO和bipyO₂;S=乙醇或水;x=1,2,3,y=0,1,2或3）和[Au（L）X₂]（L=bipyO₂;X=Cl或Br）。用元素分析、摩尔电导、紫外和红外光谱、核磁共振和热重分析等方法测定了它们的组成和性质,并对其可能的结构也进行了讨论。更多还原

【Abstract】 Ten complexes of tetrachloroauric acid hydrate or their alkali salts with the series of neutral oxo compounds RaXO(R = octyl or phenyl, X = N,P,As or S,n = 2 or 3) have been synthesized and characterized by elemental analyses, molar conductance, infrared, ultraviolet and NMR spec-troscopies, and thermogravimetric techniques. The results show that the complexes are well defined complexes of the two types. H(RaXO)x·AuCl4·Sy(RaXO = TONO, TOPO, DOSO, DPSO, TPPO, TPAsO and bipyO2,S = ethanol or water, x = 1,2 or 3,y = 0,1,2 or 3) and CAu(L)(Hal)2]Hal (L = bipyO2, Hal = Cl or Br). The possible complexes structures are discussed too.更多还原