【摘要】 以β-萘酚醛与一系列二胺缩合为配体,合成了钴的配合物。通过测定配合物在各种溶剂中吸收的氧气,得到了配合物与分子氧的摩尔比。并从各种溶剂中分离出了一系列2:1和1:1（Co/O₂）的分子氧加合物。对这些配合物和分子氧加合物进行了元素分析,红外、紫外一可见光谱和磁化率的表征,并研究了性质与结构的关系。更多还原

【Abstract】 Some coordination compounds of cobalt with Schiff base, derived by the condensation of 2-hydroxy-1-naphthaldehyde with a series of diamines have been syntheized. The ratio of cobalt/oxygen is determined by gas-volumetric measurements for absorbed oxygen. Several 2:1 and 1:1 adducts of cobalt schiff base complexes with molecular oxygen have been isolated from various solvents. All these compounds are characterized by elemental analysis, IR, UV-visible spectra and magnetic susceptibility. The relationship between properties and structures is studied.更多还原