【摘要】 以四苯基卟啉和结晶紫为敏化剂,在太阳高密度能量辐照范围内（波长500—600nm）实现了双环[2,2,1]-2,3—二羧基-2,5-庚二烯（N）异构化为四环[2,2,1,0^2.5,0^3.5]-2,3-二羧基庚烷（Q）。以四苯基卟啉钴为催化剂,可顺利完成Q向N的转化。讨论的N异构化为Q的机理中包括光敏化单线态电子转移过程。更多还原

【Abstract】 Bicycle [2,2, 1]-2,3-dicarboxy-2,5-heptadiene was synthesized (N). Photosensitized electron transfer isomerization of N to quadrocyclo[2,2,1,02.6,03.5]-2,3-dicarboxy-hepta-ne(Q) was studied. Tetraphenylporphyrin and crystal voilet were used as sensitizers. The highest optical radiation intensity (500-600nm) of solar energy coujd be storaged by the isomerization of N to Q. Q was catalyzed reversing to N by complex cobalt(Ⅱ) and tetraphenylporphyrin. The mechanism of photoisomerization was also discussed.更多还原