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催化分光光度法测定痕量钍(Ⅳ)的研究
Study on Spectrophotometric Determination of Trace Thorium (Ⅵ) in Water
【摘要】 <正> Alersandrur等研究了动力学测定钍(Ⅳ),灵敏度仅为10-7g数量级。作者发现盐酸介质中,钍(Ⅳ)能灵敏地催化过氧化氢氧化邻苯三酚红褪色的新指示反应,研究了此反应的动力学条件,建立了一种高选择性、高灵敏度的新方法,且具有操作简便快速,分析结果准确,重现性好的特点,便于推广使用。
【Abstract】 A new spectrophotometric method for determination of trace thotrum(Ⅳ) in water wasdeveloped, by utilizing decolorization reation of H2O2-Th4+-pyrogallol system which was cataliz-ed by thorium (Ⅲ). The sensitivity, recoveries and limits of determination were 6.5×10-12gTh4+/ml, 99~101% and 0~0.10μgTh4+/25ml respectively with variable coefficient of 2.1~4.2%.
- 【文献出处】 分析测试通报 ,Journal of Instrumental Analysis , 编辑部邮箱 ,1988年06期
- 【被引频次】4
- 【下载频次】9