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快速流化床丁烯氧化脱氢气体产物的最佳分布
Optimum Distribution of Gaseous Products of Oxydehydrogenation of Butene to Butadiene in a Fast Fluidized Bed
【摘要】 研究了在ф2.6cm的快速流化床上丁烯氧化脱氢制丁二烯气体产物的最佳分布。采用 H-198工业催化剂的筛下部分,颗粒平均直径为88μm,反应温度330—380℃,空速298—328h-1,氧烯比0.94—0.97,水烯比7.5—8.3,线速460—490cm/s 的反应条件。选定了气体产物最佳分布时(?)2.6cm 设备的设计尺寸,其结果丁烯的转化率和丁二烯的收率均比挡板流化床高15—25单位。
【Abstract】 This paper presents the results of experiments on the optimum distribu-tion of gaseous products in a fast fluidized bed with diameter 2.6 cm for oxyde-hydrogenation of butene to butadiene.The reaction conditions were as follows:H-198 industrial catalyst with an average diameter of dp=88μm,butene purity92.64%,reaction temperature 330—380℃,space velocity 298—328h-1,mole ratiowater to butene 7.5—8.3:1,mole ratio oxygen to butene 0.94—0.97:1,linear vel-ocity 460—490cm/s.Our conclusion is that conversion of butene and yield of bu-tadiene are 15—25% higher than that in the baffled fluidized bed.The resultsobtained are used for determining the dimension of the reactor,
- 【文献出处】 石油化工 ,Petrochemical Technology , 编辑部邮箱 ,1988年01期
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