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稀土荧光塑料的研究

A Research of Fluorescent Plastics Containing Rare-Earth Complex

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【作者】 何宜龚孟濂李源英张卫红杨燕生梁兆熙

【Author】 He Yi, Gong Menglian, Li Yuanying, Zhang Weihong, Yang Yansheng and Liang Zhaoxi (Zhongshan University)

【机构】 中山大学中山大学

【摘要】 组成为Eu(RCOCHCOR’)3L(L为有机碱)的一种稀土络合物作为荧光剂分别与PS和EVA制成荧光塑料。在低功率近紫外线灯的近紫外线(UV)辐隔下,它们能够发射波长为613nm的红色荧光。荧光强度比较高,但随UV辐照时间的增加而逐渐降低,然后趋于定值。这是络合物的配合键离解所致。这类荧光塑料具有一定的使用寿命。

【Abstract】 A rare-earth complex having composition of Eu (RCOCHCOR’)_a L(L is an organic base) was used as a fluorescer to prepare PS and EVA fluorescent plastics. The reported products can emit red fluorescence with wavelength of 613 nm under the radiation of near UV from a near UV lamp with lower power. The fluorescent intensity was stronger first, then decreased gradually with increasing UV radiation time, and approached a constant. This is attributed to the dissociation of the coordinate linkages in the complex. The products have a longer lifetime in application.

  • 【文献出处】 塑料工业 ,China Plastics Industry , 编辑部邮箱 ,1988年06期
  • 【被引频次】13
  • 【下载频次】99
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