【摘要】 锌赤铁矾是1964年在我国首次发现的一种硫酸盐类新矿物。它的实验化学式是(Zno_0.64Mg_0.27Mn_0.11Fe_0.05²⁺)_1.07Fe_1.00³⁺（SO₄）_1.96（OH）·6.61H₂O,理论分子式为ZnFe³⁺（SO₄）₂（OH）·7H₂O。本文在前人工作的基础上,利用四圆衍射仪对其结构进行了精测。根据所得实验资料,着重对如下晶体化学问题做了讨论;（1）氢键;（2）多面体的畸变;（3）原子的热运动;（4）结构和物性的关系;（5）Zn²⁺和Mg²⁺的类质同象等。同时,对锌赤铁矾的某些谱学特征和它与类同矿物的关系做了对比和讨论。更多还原

【Abstract】 Zincobotryogen is a new sulphate mineral with an experimental formula of (Zn_0.64Mg_0.27Mn_0.11Fe_0.05²⁺)_1.07Fe_1.00³⁺（SO₄）1.06)（OH）·6.61H₂O and a theoretical formula of ZnFe³⁺（SO₄）₂（OH）·7H₂O, which was found in China in 1964. Based on the previous work, its crystal structure was examined with a four-circle diffractomelet, and the following crystallochemieal problems were discussed in this papers （Ⅰ） hydrogen bond; （2） distortion of polyhedra; （3） thermal vibrations of atoms; （4） relationship between structure and physical properties; and （5） replacement of Mg by Zn. Besides, the interpretation of some spectral characteristics of zincobotryogen and the comparison between this mineral and other Similar minerals were also made.更多还原