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Ce(Ⅳ)引发丙烯酸乙酯与玉米淀粉的接枝共聚反应规律及产物酶解性能的研究——乙烯基类单体与淀粉的接枝共聚反应(Ⅲ)

Studies on the Graft Copolymerization of Ethly Acrylate onto Corn Starch and Enzymatic Degradation of Grafts ——Graft Copolymerization of Vinyl Monomers onto Starch(Ⅲ)

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【作者】 巫拱生; 贾翠红; 鲁德忠; 吴兴久; 孙艳霞;

【Author】 Wu Gongsheng, Jia Cuihong, Lu Dezhong, Wu Xingjiu and Sun Yanxia (Department of Chemistry,Jilin University)

【机构】 吉林大学化学系高分子教研室; 吉林大学化学系高分子教研室;

【摘要】 以硝酸铈铵为引发剂,研究了丙烯酸乙酯与玉米淀粉接枝共聚的反应规律。

【Abstract】 In this paper, the regularities of graft copolymerization of ethyl acrylate (EA)and corn starch using Ce4+ as initiator is reported. Our experimental results showed that the percent grafting (G%)and graft efficiency were considerably affected by Ce4+, EA, reaction temperature and time. The maximum G and E were obtained at 10~12m mol/l of Ce4+and 5~6d mol/l of EA at 40℃ in 3h.In this study, we found that S-G-PFA can be processed to give a film, it undergoes enzymatic degradation and the loss in weight is about 20% in 27 days.

  • 【文献出处】 吉林大学自然科学学报 ,Journal of Jilin University , 编辑部邮箱 ,1988年03期
  • 【被引频次】13
  • 【下载频次】68
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