【摘要】 报道了用Adler方法合成四苯基（2-硝基）卟啉（简称TP（2-NO₂）P）的Co、Ni、Mn金属配合物。用元素分析、紫外可见光谱、红外光谱、核磁共振、顺磁共振等方法表征了配合物的组成和结构。用光谱滴定法研究了配合物与含氮有机碱的加合反应和性质。更多还原

【Abstract】 The improved Adler’s method was used to prepare the complexes of tetraphenyl （2-nitro-） porphyrinstometal （abbreviation TP（2-NO₂）P·M）. The structures and compositions of the complexes were determined by elemental analysis, UV, IR, ¹H NMR and EPR. Adducts of the complexes with nitrogen-containing organic bases were studied by spectroscopic titration method.更多还原