【摘要】 用氯化亚铁、苯硫酚钠及溴化四乙基铵在乙腈溶液中,经一步反应,得到两个同分异构的化合物α-[Et₄N]₃[Fe₃（PhS）₃Cl₃Br₃]1和β-[Et₄N]₃[Fe₃（PhS）₃Cl₃Br₃]2.X 射线晶体结构测定表明,1和2的阴离子骨架为3Fe、3S 交叉排列的六元环,前者为扭船型,后者为椅型.1属单斜晶系,空间群 C2/c,晶胞参数:a=24.569（4）,b=13.504（2）,c=18.348（3）■,β=110.78（1）°.Z=4,R=0.070.2属三方晶系,空间群 Pucl,晶胞参数:a=b=13.720（3）,c=35.748（5）(■.Z=4,R=0.059.讨论了反应和结构特点.更多还原

【Abstract】 Two isomeric compounds α-[Et₄N]₃ [Fe₃（PhS）₃Cl₃Br₃]（1）and β-[Et₄N]₃[Fe₃（PhS）₃·Cl₃Br₃]（2）have been synthesized through one step reaction of iron（II）chloride withsodiun phenylthiolate and tetraethylammonium bromide in acetonitrile.The skeletonsof anions in compounds 1 and 2 are six membered rings with alternative Fe and Sarrangement,the former exists in twist boat form and the latter in chair one.The crystal of 1 is monoclinic,with space group C2/c,a=24.569（4）,b=13.504（2）,c=18.348（3）（?）,β=110.78（1）°,Z=4,R=0.070.The crystal of 2 is trigonal,withspace group P（?）c1,a=b=13.720（3）,c=35.748（5）（?）,Z=4,R=0.059.The characteri-stics of the roaction and structure have been discussed.更多还原