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铀在碱式碳酸锌固一液界面分配的台阶型吸附等温线
A Step-isothem of Uranyl Ion Distribution on the Interface of Solid-liquid at Basic Zinc Carbonate
【摘要】 本文报导铀在碱式碳酸锌吸附剂固——液界面分配的台阶型吸附等温线.它有一个“拐点”,两个“平台”.表明铀与碱式碳酸锌的阴离子交换过程是分级进行的.在pH等于7.4的条件下,铀与碱式碳酸锌的交换过程可能是R-OH+[UO2(OH)3]??R-UO2(OH)3+OH- 由分级离子交换等温线计算得到交换过程中的热焓变化.作图法求得分级离子交换平衡常数
【Abstract】 A step-isothem of uranium (Ⅵ) distribution "on the interface of solid-liquid at basic zinc carbonate-solution is studied.It has one "knee" and two "plateaus".It demonstrates that the exchange process of uranium with hydroxyl ions of basic zinc carbonate is carried by stepwiss.Under the ph=7.4, the exchange process can be expressed by R-OH+(UO2(OH)3)-??RUO2(OH)3)+OH- The equilibrium constants and enthalpy change have been culculated.
- 【文献出处】 华东师范大学学报(自然科学版) ,Journal of East China Normal University(Natural Science) , 编辑部邮箱 ,1988年04期
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