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丙烯酸β-羧乙酯-苯乙烯共聚合的研究
STUDY ON COPOLYMERIZATION OF ACRYLOXYPROPIONIC ACID AND STYRENE
【摘要】 <正> 丙烯酸酯类聚合物是一类性能优良的橡胶、涂料和粘合剂,酯的结构不同可得到性能各异的均聚物和共聚物。 丙烯酸β-羧乙酯(APA)是一种具有多种反应功能的丙烯酸酯单体,结构式为:CH2=CH—COOCH2CH2COOH,其双键可发生加成聚合,制得的大分子带有反应性酯基和羧基侧基,以其制备反应性大分子具有广泛的应用前景。我们研究了丙烯酸β-羧
【Abstract】 @-Acryloxypropionic acid and styrene copolymers were synthesized through radical copo-lymerization with AIBN and BPO as initiators. The major factors that affected the copoly-merization were studied. The copolymerization reactivity ratios of monomers were determined by YBR method and the following data were obtained:rst = 0.5863, rAPA = 0.2826,QAPA = 0.54,eAPA = 0.44.
【关键词】 丙烯酸β-羧乙酯;
共聚合;
线性化法;
竞聚率;
Q;
e值;
【Key words】 β-Acryloxypropionic acid; Copolymerization; YBR method; reactivity ratios; Q e Value;
【Key words】 β-Acryloxypropionic acid; Copolymerization; YBR method; reactivity ratios; Q e Value;
- 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,1988年04期
- 【被引频次】1
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