节点文献
新型无机离子交换剂的研究(Ⅱ)——47种金属离子在锑酸锌交换纸上的层析行为
Studies on New Inorganic Ion-Exchanger(Ⅱ)--Chromatographic Behavior of 47 Cations on Paper Impregnated with Zinc Antimonate
【摘要】 将锑酸锌无机离子交换剂制成离子交换纸,对47种金属离子的层析行为进行了研究。选用二甲亚砜(DMSO)+硝酸,DMSO+水及硝酸水溶液为展开剂,探讨了金属离子的R_f值与DMSO,硝酸浓度、离子势等之间的规律性。实验表明,选择合适的层析条件,许多离子对或组的分离是成功的。
【Abstract】 The chromatographic behavior of 47 metal ions was investigated on plain and ZnSb papers in dimethylsulfoxide-nitric acid and aqueous nitric acid systems. The relations between R f values of some metal ions and DMSO, concentration of nitric acid, ion potential, screening-loss parameters of ions were discussed. The results showed that a lot of ion-couples or groups were separated under proper conditions.
【关键词】 无机离子交换剂;
锑酸锌;
纸层析;
【Key words】 Inorgan c ion-exchanger; Znic antimonate; Paper chromatography;
【Key words】 Inorgan c ion-exchanger; Znic antimonate; Paper chromatography;
【基金】 国家自然科学基金
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1988年11期
- 【被引频次】1
- 【下载频次】50