【摘要】 <正> 前文报道的硫代磷酰二氯在三乙胺存在下与邻苯二酚反应,不仅具有理论意义,而且是合成该类磷化物的新方法。本文将继续报道硫代磷酰一氯以及其它硫代四配位磷化物与邻苯二酚反应的结果,以期进一步揭示这类反应的本质及其影响因素。 1 结果与讨论 当硫代磷酰一氯Ⅰ在三乙胺存在下与邻苯二酚反应时得到六配位磷化物Ⅱ。更多还原

【Abstract】 The reaction of a series of phosphorochloridothioates with catechol in the presence of triethylamine yields a hexacoordinated phosphorus, compound Ⅱ. Phenyl thiophosphonyl chlorides reacted with catechol to produce a pentacoordina-ted phosphorus compound Ⅴ. Phenyl. pyrophosphonothioate reacts with catechol to give Ⅱ and Ⅴ. The mechanism of these reaction were discussed, too.更多还原