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多环聚梯型共轭烃及其稳定性
Ladder-Like Polymers of Polycyclic Conjugated Hydrocarbon and its Stability
【摘要】 本文利用CNDO/2法讨论了一类新型共轭烃——多环聚梯型共轭烃存在的可能性。结果表明,对三元-五元环烃和四元-四元环烃为重复单元的直链多聚梯型共轭烃H2-(-C3C5H2-)-nH2和H2-(-C4HC4H-)-nH2,在n是偶数时体系稳定。
【Abstract】 In this paper,according to the results of CNDO/2 quantum chemistry calculation, we have discussed the possibility on a set of novel conjugated shown that, hydrocarbons, ladder-like polymers of polycyclic conjugated hydrocabons. It is when n is a even number the molecules of chain ladder-like polymers of polycyclic conjugated hydrocabons with three menbered ring-five menbered ring or four menbered ring-four menbered ring as repeated unit, H2-(-C3C5H2) or H2(C4HC4H)nH3, might be stable, which enables us to believe that the aformentioned molecules are possible potential synthesized objects.
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1988年01期
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