【摘要】 本文报道了PyH[（VO）（Bz）₂Py]Py配合物的单晶制备及其晶体结构和分子结构。该配合物晶体属三斜晶系,P₁空间群,晶胞参数为:a=12.400（5）,b=14.042（5）,c=10.441（4）,α=91.92（3）°,β=93.57（3）°,γ=74.41（3）°,V=1847.7（1.2）（?）³,Z=2。最后一致性因子为R=0.045,讨论了结构与性质。更多还原

【Abstract】 The vanadium(Ⅴ) complex, PyH[VO(Bz)2Py]Py, has been prepared from NaVO3, H2Bz and Py. The single crystal belongs to triclinic in space group, P1, with unit cell constants, α=12.400(5)A, b= 14.042(5)A, c= 10.441(4)A, α=91.92(3)°,β= 93.57(3)°, γ=74.41(3)°, V=1874.7(1,2)A3, Z = 2.Least-spuare refinement has led to a final R value of 0.0450.The coordination number of vanadium is equal to 6, and it is constructed as a distored octahedral form by one N atom and five O atoms. That complex is a cis-isomer.更多还原