节点文献
[L1-2NiX2]、[LNiL’]和[LNiL’]2+型有机镍配合物(X=Cl、Br、I)电化学性质的研究
Electrochemistry of Complexes of the Type [LNiL’], [L1-2NiX2 ]and [LNiL’ ]+2Where X=Cl,Br,I
【摘要】 配合物的结构、配合方式、配合体性质、金属与配体间的键性以及溶剂的性质等因素对有机 镍配合物的电极电势都有影响,具螯合配位结构的配合物表现出很高的电化学稳定性。
【Abstract】 This paper deals with the electrode potentials of organonickel complexes, which are dependent on the structure of complex, the type of coordination, the property of the ligand, the bond of M-L and the property of the solvent.The complexes with type LNiL’ have a higher stability in electrochemistry .The re- ductvie and oxidative wave were formed from Ni(0 ) through to Ni(Ⅳ) in the CV process.
【关键词】 有机镍配合物;
配位效应;
循环伏安法;
【Key words】 organonickel complex; coordination effect; cyclic voltammetry;
【Key words】 organonickel complex; coordination effect; cyclic voltammetry;
- 【文献出处】 福州大学学报(自然科学版) ,Journal of Fuzhou University(Natural Sciences Edtion) , 编辑部邮箱 ,1988年04期
- 【被引频次】1
- 【下载频次】37