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金属与试剂分别过量时形成不同颜色配合物组成的探讨
A NEW MATHEMATICAL MODEL FOR COUNTING REAL COMPOSITION OF THE COMPLEX OF FORMING DIFFERENT COLOUR IN EXCESS OF LIGAND OR METAL WITH SPECTROPHOTOMETRIC DATA
【摘要】 本文提出一种新的数学模型法,该法直接通过计算,就可得出金属与试剂分别过量时形成不同颜色配合物的真正组成。
【Abstract】 The method is based on the effect of dilution on the dagree of dissociation(αandβ)of complexes(MB and M2B2). Once the correct values m and n have been known, it is possible to solve a problem in the real composition of complexes. The results for two wellstudied systems with zirconium, lead and xylenol orange are shown as demonstrations.
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1988年11期
- 【被引频次】1
- 【下载频次】55