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聚乙烯醇存在下钌(Ⅱ)-氯化亚锡-结晶紫高灵敏显色反应体系的研究
SENSITIVE REACTION OF THE SYSTEM OF RUTHENIUM(Ⅱ)-TIN(Ⅱ) CHLORIDE-CRYSTAL VIOLET IN THE PRESENCE OF POLYVINYL ALCOHOL
【摘要】 本文研究了在聚乙烯醇存在下钌(Ⅱ)-氯化亚锡-结晶紫离子缔合体系的高灵敏显色反应。离子缔合物的最大吸收峰位于550nm处,摩尔吸光系数为1.1×106L.mol-1cm-1.钌含量在0.2—2.8μg/25mL范围内符合比尔定律。对外来离子的干扰和分离进行了研究。拟定的方法可用于矿石和一些低品位贵金属物料中钉的分析。
【Abstract】 A highly sensitive spectrophotometric method for the determination of Ru has been developed. The molar absorptivity is 1.1×10~6 L·mol~-1·cm~-1 at 550nm. Beer's law is obeyed for 0.2—2.8μg/25ml of Ru. Interference and separation of diverse ions are also investigated. The method is applicable to the determination of Ru in some precious metal samples.
【关键词】 聚乙烯醇;
钌;
氯化亚锡;
结晶紫;
分光光度;
【Key words】 Polyvinyl alcohol; Ruthenium; Tin (Ⅱ) chloride; Crystal violet; Colour reaction;
【Key words】 Polyvinyl alcohol; Ruthenium; Tin (Ⅱ) chloride; Crystal violet; Colour reaction;
- 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1988年10期
- 【被引频次】8
- 【下载频次】25