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红外光谱法测定丙烯酸酯悬浮共聚竞聚率

DETERMINATION OF SUSPENSION COPOLYMER ACTIVITY RATIOS OF ACRYLATE MONOMERS USING IR-METHOD

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【作者】 华载文; 陈水林; 张尧君; 沈定南;

【Author】 Hua Zaiwen, Chen Shuilin, Zhang Yaojun and Shen Dingnan (Department of Textile Chemical Technology, CTU etc.)

【机构】 中国纺织大学纺织化学工程系应用化学研究室; 中国纺织大学纺织化学工程系应用化学研究室; 上海第二丝绸印染厂;

【摘要】 本文对丙烯酸丁酯和丙烯酸乙酯的共聚合作了研究.并采用均聚共混方法制备标准样品,由红外光谱法分别测定标准样品和共聚样品中乙基和羧基的相对峰高。从而测得共聚大分子链节比(摩尔),最后用YBR法求得二元共聚竞聚率,从而判断丙烯酸丁酯和丙烯酸乙酯的共聚组成。

【Abstract】 In this paper a study on the suspension copolymerization of acrylates of ethyl and butyl was made, using blends of homopolymers of the two monomers as standard samples. In their IE-spectra, relative heights of the characteristic absorption crests of the carbonyl-and ethyl groups in both standard samples and copolymers were taken and the ratios of the two monomers contained in the copolymers were calculated. Finally the suspension copolymer activity ratios of these two monomers were determined by the YBR-method and the copolymerization features of the ethyl-and butyl acrylates were estimated.

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