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离子镀Ni-Cr合金膜300℃的氧化

THE OXIDATION OF ION PLATED Ni-Cr ALLOY FILM AT 300℃

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【作者】 王淑荷; 陈秀芝; 闻立时;

【Author】 WANG Shuhe;CHEN Xiuzhi;WEN Lishi(Institute of Metal Research,Academia Sinica,Shenyang)

【机构】 中国科学院金属研究所; 中国科学院金属研究所;

【摘要】 采用 LAS 3000表面分析系统研究了离子镀 Ni-Cr 合金膜300℃的氧化行为。结果表明,Fe,Cr,Al,被氧化,形成 Cr2O3,Fe2O3和 Al2O3等氧化物,Ni 基本上未被氧化。对于不同的氧化时间,氧化层成分的变化规律基本一致,氧化过程遵从对数规律。形成的氧化膜薄且致密,氧化速度缓慢,有较好的抗氧化性。

【Abstract】 The oxidation behaviorr of ion plated Ni-Cr alloy film at 300℃ wasinvestigated by using LAS 3000 surface analysis system.The resultsshowed that EB ion plated Ni-Cr alloy film was oxidized at 300℃.Theoxide of Fe,Cr,Al formed during oxidation,were Cr2O3,Fe2O3 and Al2O3but oxide of Ni was not found.The composition variation of oxide layer fordifferent oxidation durations follow a similar rule.In all cases,there existsan oxygen concentration peak in composition profile of Oxide layer.Thereis a transitional zone between oxide layer and alloy film.The oxide layerthickness increases,logarithmically with oxidation time.A logarithmic ratelaw was obtained.The ion plated Ni-Cr alloy film has very dense oxidelayer and good oxidation resistance In the summary,Ni-Cr alloy film withthickness of several microns can be used as an oxidation resistant protectivefilm in temperature range about 300℃

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