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用飞行时间质谱仪对HMX热分解机理的研究
STUDY OF THE MECHANISM OF THERMAL DECOMPOSITION OF CYCLOTETRAME- THYLENE TETRANITRAMINE BY USING TIME OF FLIGHT MASS SPECTROMETER
【摘要】 本文的主要工作是用ZHP-6型飞行时间质谱仪研究了环四亚甲基四硝胺(HMX)的热分解,并采用专用的热分解反应装置较好的排除了HMX升华气体产物对其热分解产物的影响。从而取得了在不同温度下HMX热分解产物的图谱,并对HMX热分解的反应机理提出了新的观点。
【Abstract】 Studies on the thermal decomposition of cyciotetrametylone tetrani-tramine(HMX) were preformed by use time of flight mass spectrometer. In order to prevent the sublimated HMX entering the ion source, a decomposition reactor was applied. The mass spectrums of decomposition of HMX with different temperatures were obtained. A new view point of mechanism on the thermal decomposition of HMX was gived.
【关键词】 飞行时间质谱仪;
热分解;
反应机理;
质谱图;
奥克托金;
【Key words】 time of flight mass spectrometer; thermal decomposi t ion; mechanism reaction; mass spectrometer; HMX.;
【Key words】 time of flight mass spectrometer; thermal decomposi t ion; mechanism reaction; mass spectrometer; HMX.;
- 【文献出处】 北京工业学院学报 ,Journal of Beijing Institute of Technology , 编辑部邮箱 ,1988年03期
- 【被引频次】1
- 【下载频次】81