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1Cr18Ni9Ti奥氏体不锈钢在Cl--H2S-NH3-CN--H2O介质中应力腐蚀的探讨

A Study of SCC Behaviours of 1Cr18Ni9Ti Austenitic Steel in CI--H2S-NH3-CN--H2O Environments

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【作者】 张树霞; 左禹; 朱晓红;

【Author】 Zhang Shuxia, Zuo Yu, Zhu Xiaohong (Department of Applied Chemistry)

【机构】 北京化工学院应用化学系; 北京化工学院应用化学系;

【摘要】 本文通过恒变形U形腐蚀实验法,研究了1Cr18Ni9Ti奥氏体不锈钢在Cl—H2S—NH3—CN-—H2O介质中应力腐蚀(SCC)及其影响因素,实验结果表明,材料在中性,特别是酸性介质中,易发生SCC,在碱性介质中,未发现SCC,在酸性介质中,Cl-和H2S,CN-起加速SCC作用.

【Abstract】 The SCC susceptibility for 1Cr18Ni9Ti stainless steel in aqueous solutions with H2S, NaCl, NaCN and NH3 additions is investigated by using constant-strain U-bend specimens. The results show that the material is susceptible to SCC when the pH value of the solution is lower thah or equal to 7. No SCC is found for solutions with pH values higher than 7. H2S is responsible for the cracking and Cl- and CN- can promote the cracking processes The effects of various additions were discussed.

  • 【文献出处】 北京化工学院学报(自然科学版) , 编辑部邮箱 ,1988年02期
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