【摘要】 本文根据同时平衡原理和电中性原理对Sb（Ⅲ）-Cl^--H₂O系,Sb（Ⅲ）-Me（Ⅰ）-Cl^--H₂O系和Sb（Ⅲ）-Zn（Ⅱ）-Cl^--H₂O系进行了常温下水解平衡的热力学分析.计算及绘制了[Sb³⁺]_T,[H⁺]与[Cl^-]_T,[Me⁺]或[Zn²⁺]的热力学关系图.经验证,彼此符合较好.又将计算及实验数据分别回归拟合,得出了相应的数模关系.更多还原

【Abstract】 In terms of the principles of simultaneous chemical equilibrium and electronic charge neutrality, the thermodynamic analyses of hydrolytic equilibria at room temperature have been made for the systems of Sb（Ⅲ）-C1^--H₂O, Sb（Ⅲ）-Me（Ⅰ）-Cl-H₂O and Sb（Ⅲ）-Zn（Ⅱ）-Cl^--H₂O in this work. The calculation of thermodynamic data and the ploting of [Sb³⁺]_T or [H⁺] versus [C1^-]_T and [Meⁿ⁺] on the hydrolytic equilibria in the systems were carried out. The obtained data and curves have been correlated with the experimental data, and there is a good agreement between them. The respective regressions of calculated and experimental data have given the relationship of the numeral models.更多还原