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用三烷基(C6-C8)氧膦(TRPO)萃取-液体闪烁计数法测定水溶液中微量α核素的研究

THE STUDY ON DETERMINATION OF TRACE a-NUCLIDE CONTENTS IN AQUEOUS SOLUTION WITH TRPO SOLVENT EXTRACTION-LIQUID SCINTILLATION COUNT METHOD

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【作者】 周顺利郑华铃陈树铭王守忠焦荣洲樊诗国刘秉仁

【Author】 Zhou Shunli Zheng Hualing Chen Shuming(Beijing Institute of Nuclear Engineering)Wang Shouzhong Jiao RongzhouFan Shiguo Liu Bingren(Institute of Nuclear Energy Technology,Tsinghua University, Beijing)

【机构】 北京核工程研究设计院清华大学核能技术研究所清华大学核能技术研究所 北京北京北京

【摘要】 本工作用三烷基氧膦(TRPO)作萃取剂,二甲苯为溶剂,2.5-二苯基噁唑为闪烁体研究了TRPO及杂质元素的猝灭效应,结果表明萃取-液体闪烁计数法用于测量大量杂质元素及氨羧络合剂中的233U,239Pu,241Am微量α核素具有简便、迅速,灵敏度高等优点。

【Abstract】 The solvent extraction-liquid scintillation count method has been studied, TRPO has been used as the extractant, dimethylbenzol as the diluent, 2.5-di?phenyloxazole as the scintillator. The quenching effects caused by TRPO or other impurity elements have been studied. The results appear that this method can determine trace a-nuclide contents (238U, 239pu, 241Am2) with a large quantity of impurity elements and amino-polycarboxylic acid. The determination can be done simply, quickly and sensitively.

  • 【文献出处】 中国核科技报告 ,China Nuclear Science and Technology Report , 编辑部邮箱 ,1987年00期
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