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某些1-辛基-3,3-二甲基吲哚啉螺苯并吡喃的合成和光致变色性质
SYNTHESIS AND PHOTOCHROMIC PROPERTIES OF SOME 1-OCTYL-3,3-DIMETHYLINDOLINOSPIROPYRANS
【摘要】 <正> 取代的吲哚啉螺苯并吡喃具有光致变色性质,在光信息显示和记录等现代技术领域已取得初步应用。以往的工作表明,这类化合物的光致变色性质与分子中的取代基有密切关系。氮上有长链烷基的吲哚啉螺苯并吡喃已有报道。我们曾考察过Ⅲa(R1=H,
【Abstract】 The title compounds(Ⅲa, R1 = H, R2 = NO2, Ⅲb, R1 = NO2,R2 = H, Ⅲc,R1 = Cl,R2 = NO2,Ⅲb, R1 = Br,R2 = NO2, Ⅲ?, R1 = R2 = NO2) were prepared by condensation of 1-octyl-3,3-dimethyl-2-methyleneindoline (Ⅰ) and substituted salicylaldehydes (Ⅱ) in anhydrousethanol. Photochromic properties of these compounds were investigated by UV/VIS spectrameasurement and photochromic film obtained from Ⅲa -? Compounds Ⅲa and Ⅲc-? arefound to be good photochromic reagents.
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1987年02期
- 【被引频次】2
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