【摘要】 <正> 癸二酸是重要的化工原料。至今国内外工业上均采用蓖麻油为原料生产癸二酸。人们正在积极开发新的原料合成癸二酸。国内在铂阳极上用己二酸单甲酯电化学合成癸二酸已获得了较高收率93％。因铂价格昂贵,要实现工业化还较困难。本文通过测定石墨电极的极化曲线,探索石墨成为电极材料的可能性。更多还原

【Abstract】 In this paper we have attemptedto find the possibility of electrochemical approachto prepare dimethyl ester of decanedioic acid from monomethyl ester of adipic acid onthe graphite anode in place of platinum. It was found that the overpotential of the oxi-dation reaction on graphite was about 1V lower than that on platinum electrode. Theyield of dimethyl ester was 15--30%.更多还原